表 2 沉香样品GC-MS分析结果①
Tab.2
The GC-MS analysis results of agarwood samples
编号 No. |
化合物Compound |
分子式 MF |
分子质量 MW |
匹配度 Matching |
相对含量 Relative amount (%) |
A型 A type |
B型 B type |
1 |
4-苯基-2-丁酮4-phenyl-2-butanone |
C10H12O |
148 |
95 |
0.52 |
0.45 |
2 |
榄香醇Elemol△ |
C15H26O |
222 |
92 |
0.20 |
|
3 |
(2R-cis)1, 2, 3, 4, 4a, 5, 6, 7-八氢-α, α, 4a, 8-四甲基-2-萘甲醇(2R-cis)1, 2, 3, 4, 4a, 5, 6, 7-octahydro-α, α, 4a, 8-tetramethyl-2-naphthalene methanol△ |
C15H26O |
222 |
93 |
0.82 |
|
4 |
沉香螺旋醇Agarospirol△ |
C15H26O |
222 |
89 |
0.40 |
0.26 |
5 |
沉香雅槛蓝醇(-) Jinkoh-eremol△ |
C15H22O2 |
222 |
92 |
0.19 |
0.42 |
6 |
枯树醇Kusunol (valerianol)△ |
C15H26O |
222 |
91 |
2.07 |
0.99 |
7 |
十氢二甲基甲乙烯基萘酚Neointermedeol△ |
C15H26O |
222 |
90 |
| 0.95 |
8 |
[2R-(2α, 4aα, 8aβ)]1, 2, 3, 4, 4a, 5, 6, 8a-八氢-α, α, 4a, 8-四甲基-2-萘甲醇[2R-(2α, 4aα, 8aβ)]1, 2, 3, 4, 4a, 5, 6, 8a-octahydro-α, α, 4a, 8-tetramethyl-2-naphthalene methanol△ |
C15H26O |
222 |
91 |
2.11 |
0.55 |
9 |
1-十二碳烯1-dodecene |
C12H24 |
168 |
92 |
0.65 |
0.43 |
10 |
1-十四碳烯1-tetradecene |
C14H28 |
196 |
95 |
0.31 |
|
11 |
1, 2, 3, 4, 4a, 5, 6, 7-八氢-1, 4a-二甲基-7-(2-羟基-1-甲基乙基)-2-萘酚1, 2, 3, 4, 4a, 5, 6, 7-octhydro-1, 4a-dimethyl-7-(2-hydroxy-1-methyl ethyl)-2-naphthalenol△ |
C15H28O2 |
240 |
85 |
1.56 |
0.91 |
12 |
艾里莫芬9, 11(13)-二烯-12-醇Eremophila-9, 11(13)-dien-12-ol△ |
C15H24O |
220 |
93 |
0.25 |
0.36 |
13 |
2, 4-二叔丁基苯酚2, 4-bis(1, 1-dimethylethyl)-phenol |
C14H22O |
206 |
92 |
| 0.74 |
14 |
新紫蜂斗菜烯Neopetasane△ |
C15H22O |
218 |
85 |
| 1.66 |
15 |
(-)-7βH-艾里莫芬-4α, 11-二醇(-)-7βH-eudesmane-4α, 11-diol△ |
C15H28O2 |
240 |
86 |
2.62 |
5.35 |
16 |
异白木香醇Isobaimuxinol△ |
C15H26O2 |
238 |
89 |
| 0.30 |
17 |
白木香醇Baimuxinol△ |
C15H26O2 |
238 |
86 |
| 0.26 |
18 |
二氢卡拉酮Dihydrokaranone△ |
C15H22O |
218 |
83 |
| 1.02 |
19 |
2, t-3-二甲基-2-(3-甲基-2-丁烯基)-1-环己酮2, t-3-dimethyl-r-2-(3-methyl-2-butenyl)-1-cyclohexanone△ |
C13H22O |
194 |
88 |
| 2.30 |
20 |
白木香醛Baimuxinal△ |
C15H24O2 |
236 |
92 |
0.89 |
5.35 |
21 |
瓦伦萨-1(10), 8-二烯-11-醇Valenca-1(10), 8-dien-11-ol△ |
C15H24O |
220 |
86 |
0.63 |
3.79 |
22 |
7α-H-9(10)-烯-11, 12-环氧-8-氧艾里莫芬烷7α-H-9(10)-ene-11, 12-epoxy-8-oxoeremophilane△ |
C15H22O2 |
234 |
89 |
1.04 |
4.70 |
23 |
1, 2-苯二羧酸二(2-甲基乙基)酯1, 2-benzenedicarboxylic acid bis(2-methoxyethyl) ester |
C14H18O6 |
282 |
81 |
| 6.22 |
24 |
(+)-9-羟基-芹子-3, 11-二烯-14-醛(+)-9-hydroxy-selina-3, 11-dien-14-al△ |
C15H22O2 |
234 |
84 |
0.66 |
1.27 |
25 |
芹子-3, 11-二烯-12, 15-二醛Selina-3, 11-diene-12, 15-dial△ |
C15H20O2 |
232 |
83 |
1.43 |
|
26 |
1, 5-联苯-3-戊酮1, 5-diphenyl-3-pentanone |
C17H18O |
238 |
88 |
0.33 |
|
27 |
β-桉叶油醇β-eudesmol△ |
C15H26O |
222 |
82 |
0.90 |
|
28 |
(Z, Z)-9, 12-十八烷二烯酸甲酯(Z, Z)-9, 12-octadecadienoic acid methyl ester |
C19H34O2 |
294 |
91 |
| 0.62 |
29 |
9-硬脂酸甲酯(Z)-9-octadecenoic acid methyl ester |
C19H36O2 |
296 |
91 |
| 1.39 |
30 |
正三十七醇1-heptatriacotanol |
C37H76O |
537 |
90 |
0.66 |
1.66 |
31 |
1, 5-二苯基-1-五亚乙基六胺-3-酮1, 5-diphenyl-1-penten-3-one |
C17H16O |
236 |
83 |
0.84 |
|
32 |
(-)-1, 5, 8, 12-二环氧-愈创木-12-酮(-)-1, 5, 8, 12-diepoxy-guaiacol-12-one△ |
C15H22O3 |
250 |
80 |
0.56 |
|
33 |
2-(2-苯乙基)色酮2-(2-phenylethyl)chromone* |
C17H14O2 |
250 |
92 |
25.16 |
5.97 |
34 |
2-[2-(4-甲氧基)苯乙基]色酮2-[2-(4-methoxy)phenylethyl]chromone* |
C18H16O3 |
280 |
89 |
0.30 |
|
35 |
6-甲氧基-2-(2-苯乙基)色酮6-methoxy-2-(2-phenylethyl)chromone* |
C18H16O3 |
280 |
90 |
16.31 |
6.58 |
36 |
5, 8-二羟基-2-(2-苯乙基)色酮5, 8-dihydroxy-2-(2-phenylethyl)chromone* |
C17H14O4 |
282 |
89 |
1.48 |
3.08 |
37 |
2-[2-(2-羟基)苯乙基]色酮2-[2-(2-hydroxyphenyl)ethyl]chromone* |
C17H14O3 |
266 |
95 |
0.27 |
|
38 |
6-羟基-2-(2-苯乙基)色酮6-hydroxy-2-(2-phenylethyl)chromone* |
C17H14O3 |
266 |
93 |
| 1.80 |
39 |
(Z)-9-十八碳烯酸-2-羟基-1-(羟基甲酯)乙酯(Z)-9-octadecanoic acid-2-hydroxy-1-1(hydroxymethyl ester)ethyl este |
C21H40O4 |
356 |
89 |
0.21 |
0.41 |
40 |
硬脂酸乙烯基酯Octadecanoic acid ethenyl ester |
C20H38O2 |
310 |
88 |
5.18 |
|
41 |
5-羟基-6-甲氧基-2-(2-苯乙基)色酮5-hydroxy-6-methoxy-2-(2-phenylethyl)chromone* |
C18H16O4 |
296 |
83 |
0.21 |
0.43 |
42 |
6-甲氧基-2-[2-(4-甲氧基)苯乙基]色酮6-methoxy-2-[2-(4-methoxyphenyl)ethyl]chromone* |
C19H18O4 |
310 |
86 |
3.63 |
3.76 |
43 |
6-甲氧基-2-[2-(3-甲氧基)苯乙基]色酮6-methoxy-2-[2-(3-methoxyphenyl)ethyl]chromone* |
C19H18O4 |
310 |
86 |
2.64 |
|
44 |
6, 7-二甲氧基-2-(2-苯乙基)色酮6, 7-dimethoxy-2-(2-phenylethyl)chromone* |
C19H18O4 |
310 |
95 |
7.60 |
16.11 |
45 |
6-甲氧基-2-[2-(3-羟基-4-甲氧基)苯乙基]色酮6-methoxy-2-[2-(3-hydroxy-4-methoxyphenyl)ethyl]chromone* |
C19H18O5 |
326 |
93 |
0.34 |
0.73 |
46 |
6-甲氧基-2-[2-(3-甲氧基-4-羟基)苯乙基]色酮6-methoxy-2-[2-(3-methoxy-4-hydroxyphenyl)ethyl]chromone* |
C19H18O5 |
326 |
92 |
0.24 |
|
47 |
6, 7-二甲氧基-2-[2-(4-甲氧基)苯乙基]色酮6, 7-dimethoxy-2-[2-(4-methoxyphenyl)ethyl]chromone* |
C20H20O5 |
340 |
89 |
1.04 |
0.77 |
48 |
(3β)-麦角-5-烯-3-醇(3β)-ergost-5-en-3-ol |
C28H48O |
400 |
88 |
0.19 |
|
49 |
豆甾-5, 22-二烯-3β-醇Stigmasta-5, 22-dien-3β-ol |
C29H48O |
412 |
89 |
1.76 |
1.17 |
50 |
γ-谷甾醇γ-sitosterol |
C29H50O |
414 |
88 |
1.78 |
0.88 |
总计Total |
87.98 |
83.64 |
色酮类Chromones |
59.22 |
39.23 |
倍半萜类Sesquiterpenes |
16.66 |
31.18 |
色酮+倍半萜Chromones + Sesquiterpenes |
75.88 |
70.41 |
①*:2-(2-苯乙基)色酮类化合物2-(2-phenyleyhyl)chromone derivatives;△:倍半萜类化合物Sesquiterpenes.
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